Solar Panel Splits Water to Produce Hydrogen 

A research team in Belgium says its prototype panel can produce 250 liters of hydrogen gas per day

 Maria Gallucci

Photo: Tom Bosserez/KU Leuven

Solar panels are multiplying on rooftops and in gardens worldwide as communities clamor for renewable electricity. But engineers in Belgium say the panels could do more than keep the lights on—they could also produce hydrogen gas on site, allowing families to heat their homes without expanding their carbon footprints.

A team at Katholieke Universiteit Leuven, or KU Leuven, says it has developed a solar panel that converts sunlight directly into hydrogen using moisture in the air. The prototype takes the water vapor and splits it into hydrogen and oxygen molecules. If it scales successfully, the technology could help address a major challenge facing the hydrogen economy.

Hydrogen, unlike fossil fuels, doesn’t produce greenhouse gas emissions or air pollution when used in fuel-cell-powered vehicles or buildings. Yet nearly all hydrogen produced today is made using an industrial process that involves natural gas, and this ultimately pumps more emissions into the atmosphere.

A small but growing number of facilities are producing “green” hydrogen using electrolysis, which splits water molecules using electricity—ideally from renewable sources such as wind and solar. Other researchers, including the team in Belgium, are developing what’s called direct solar water-splitting technologies. These use chemical and biological components to split water directly on the solar panel, forgoing the need for large, expensive electrolysis plants.

“Finding a way to create hydrogen in some easier or more efficient way is maybe a Holy Grail quest,” says Jim Fenton, who directs the Florida Solar Energy Center at the University of Central Florida.

KU Leuven sits on a grassy campus in Flanders, the Dutch-speaking northern region of Belgium. Earlier this month, professor Johan Martens and his team at the Centre for Surface Chemistry and Catalysis announced their prototype could produce 250 liters of hydrogen per day on average over a full year, which they claim is a world record. A family living in a well-insulated Belgian house could use about 20 of these panels to meet their power and heating needs during an entire year, they predict.

The solar panel measures 1.65 meters long—roughly the height of a kitchen refrigerator, or this reporter—and has a rated power output of about 210 watts. The system can convert 15 percent of the solar energy it receives into hydrogen, the team says. That’s a significant leap from 0.1 percent efficiency they first achieved 10 years ago. (Separately, international researchers last year said they achieved 19 percent efficiency in producing hydrogen from direct solar water splitting.)

“The most difficult part is getting the water out of the air.”

However, Martens’s lab was tight-lipped about its technology. Tom Bosserez, a post-doctoral researcher, declined to disclose any specifics, citing intellectual property concerns. He says only that the lab specializes in “catalysts, membranes, and adsorbents.”

“Using our expertise in this area, we were able to develop a system that is very efficient in taking water from the air and splitting it into hydrogen by using solar energy,” Bosserez wrote in an email. Asked about some of the engineering challenges they faced during a decade of development, he says, “The most difficult part is getting the water out of the air.”

Academic papers offer scattered clues about the technology, though Bosserez says their research “goes beyond what we publish.” In recent years, the engineers have studied the efficacy of a variety of materials, including porous, multi-junction silicon solar cells with “micrometer-scale pore dimensions”; thin-film catalysts made from manganese (III) oxide; and a poly (vinyl alcohol) anion exchange membrane involving a potassium hydroxide solution and nickel-based catalysts.

Martens says generally that his team is using “cheap raw materials” in lieu of precious metals and other expensive components. “We wanted to design something sustainable that is affordable and can be used practically anywhere,” he told VRT, a public broadcasting network in Belgium.

Researchers plan to field test their prototype at a house in the rural town of Oud-Heverlee. Hydrogen would be stored in a small, underground pressure vessel during the summer months, then pumped throughout the house during the winter. If all goes according to plan, Martens says the team could install 20 panels at the house, or build a larger neighborhood system to allow other families to use the “green” hydrogen.

Fenton, of the Florida Solar Energy Center, says it’s far too early to determine whether or when hydrogen-producing solar panels could become economically viable. The technology is still in the very early development stage, and—particularly in the United States—existing heating fuels such as natural gas are relatively cheap. However, as countries work to address climate change, and as more communities install local renewable energy infrastructure like rooftop solar, he sees a potential role for these hydrogen systems.

“If the application works out, it might lend itself very nicely to generating hydrogen that I could store and use for the heating of my house, for cooking, maybe run it in my fuel-cell car,” Fenton says. “It’s these futuristic kinds of opportunities. But it’s still something we need to prepare for.”